Sandia Optical
Resources / Common polymers

The polymers Sandia molds and turns, side by side.

Refractive index, dispersion, Tg, water uptake, transmission band, and birefringence character for the optical polymers we run. Where polymer is the wrong answer, the watch-for line says so — that earns trust faster than overselling.

Comparison

Side by side

Industry-typical optical-grade properties. Specific grade choice (e.g. Zeonex E48R vs 480R, TOPAS 5013L-10 vs 6013S-04) drives Tg, flow, and water-uptake within the cyclic-olefin families; confirm against current supplier datasheets before locking process.

Optical polymers — typical properties

Polymer Abbr. nd vd Tg Water 24h Transmission Birefringence
Optical PMMA PMMA 1.491 57.4 105 °C 0.3% / 24h 380–1100 nm Low–moderate; sensitive to pack/hold
Optical Polycarbonate PC 1.585 30.0 147 °C 0.15% / 24h 400–1600 nm High; stress-optic coefficient is large
Cyclic Olefin Copolymer (TOPAS) COC 1.533 56.2 78–178 °C (grade-dependent) <0.01% / 24h 380–1600 nm Very low
Cyclic Olefin Polymer (Zeonex) COP 1.530 55.8 123–163 °C (grade-dependent) <0.01% / 24h 380–1600 nm Very low
Zeonex E48R E48R 1.531 55.8 139 °C <0.01% / 24h 380–1600 nm Very low
OKP-1 / OKP-4 (polyester high-index) OKP 1.642–1.654 21.5–23.2 108–127 °C 0.2–0.4% / 24h 420–1600 nm Low–moderate
Polysulfone PSU 1.633 23.3 185 °C 0.3% / 24h 420–1600 nm Moderate
Optical Polystyrene PS 1.590 30.8 100 °C 0.05% / 24h 390–1100 nm Moderate; orientation-driven
Per polymer

Typical use, and what to watch for

Polymer

Optical PMMA (PMMA)

nd
1.491
vd
57.4
Tg
105 °C
Transmission
380–1100 nm
Water 24h
0.3% / 24h
Birefringence
Low–moderate; sensitive to pack/hold

Cost-driven visible imaging, illumination optics, light pipes, and consumer eyewear where environment is mild. Surface scratch resistance and humidity uptake; not for sustained high-temperature operation or outdoor UV without protective coating.

Polymer

Optical Polycarbonate (PC)

nd
1.585
vd
30.0
Tg
147 °C
Transmission
400–1600 nm
Water 24h
0.15% / 24h
Birefringence
High; stress-optic coefficient is large

Impact-resistant covers, safety eyewear, automotive light guides, and parts that need thermal headroom. Birefringence-driven contrast loss in imaging paths; demands disciplined gating and process for low-stress molded form.

Polymer

Cyclic Olefin Copolymer (TOPAS) (COC)

nd
1.533
vd
56.2
Tg
78–178 °C (grade-dependent)
Transmission
380–1600 nm
Water 24h
<0.01% / 24h
Birefringence
Very low

Medical and diagnostic optics, low-moisture-uptake parts, NIR sensors, and biophotonic disposables. Grade selection drives Tg over a wide range; specify the exact grade (e.g. 5013L-10, 6013S-04) before locking process.

Polymer

Cyclic Olefin Polymer (Zeonex) (COP)

nd
1.530
vd
55.8
Tg
123–163 °C (grade-dependent)
Transmission
380–1600 nm
Water 24h
<0.01% / 24h
Birefringence
Very low

DMS/OMS imaging in automotive, mobile camera modules, AR/VR waveguide adjacents, low-stress aspheres. Static charge handling and tool venting; chemical compatibility narrower than PMMA.

Polymer

Zeonex E48R (E48R)

nd
1.531
vd
55.8
Tg
139 °C
Transmission
380–1600 nm
Water 24h
<0.01% / 24h
Birefringence
Very low

Workhorse grade for low-birefringence visible and NIR imaging; common in DMS lens stacks. Confirm grade vs newer Zeonex 480R for moisture, flow, and Tg trade-offs.

Polymer

OKP-1 / OKP-4 (polyester high-index) (OKP)

nd
1.642–1.654
vd
21.5–23.2
Tg
108–127 °C
Transmission
420–1600 nm
Water 24h
0.2–0.4% / 24h
Birefringence
Low–moderate

High-index flint element of a polymer doublet — pairs with COP/COC crown to control chromatic aberration without glass. Higher dispersion and slightly narrower visible transmission than COP; pair grade selection with crown polymer.

Polymer

Polysulfone (PSU)

nd
1.633
vd
23.3
Tg
185 °C
Transmission
420–1600 nm
Water 24h
0.3% / 24h
Birefringence
Moderate

High-temperature optical and electro-optical parts (sterilization-tolerant, autoclave-survivable medical components). Amber base tint shifts color balance; not for neutral-photometric imaging without correction.

Polymer

Optical Polystyrene (PS)

nd
1.590
vd
30.8
Tg
100 °C
Transmission
390–1100 nm
Water 24h
0.05% / 24h
Birefringence
Moderate; orientation-driven

Low-cost imaging, light-pipe segments paired with PMMA as a high-index flint analogue in commodity stacks. UV yellowing and limited environmental durability; rarely the right answer outside cost-driven consumer programs.

Picking the wrong polymer is the cheapest mistake to undo at DFM.

Send the prescription and the operating envelope. We will tell you when polymer wins, when glass wins, and which grade earns its place in your stack.

Start a polymer-material conversation